[Editors]
[Call for Papers][Announced Papers]
[Published Papers] [Leading Review Papers] [List of Keywords]
Rationale for
the Special Issue “Grunwald-Winstein Equations – 60 Years & Counting”
log(k/k0) = mY
log(k/k0) = lN +mY | Dear
Colleague,
IJMS
has agreed to a special issue commemorating the 60th anniversary of the
original Grunwald-Winstein Equation. In recent years several
papers have highlighted its usefulness in Physical Organic Chemistry,
especially appreciating its contribution in providing information
utilized in the determination of mechanisms of reaction of useful
organic compounds.
I now strongly urge you to take
advantage of this forum provided by IJMS, to submit your research
articles or review commentaries on LFER’s, and studies on solvent
interactions, for possible publication in this journal during 2008.
Thank you, Malcolm J. D’Souza Guest Editor
|
Editors
Guest Editor
Prof. Dr. Malcolm J. D'Souza
Professor of Chemistry, Wesley College, 120 North State St., Dover, DE 19901, USA
Tel.: +1 302-736-2528; Fax: +1 302-736-2301
E-mail: [email protected]
URL: http://www.dbi.udel.edu/People/dsouzabio.html
Keywords
Topics
of special interest include, but are not strictly limited to, the following:
- Grunwald-Winstein Equation
- Solvolysis
- LFER (Linear Free Energy Relationship)
- Mechanisms of Reaction
- Rates of reaction
- Solvent polarity
- Solvent nucleophilicity
- Solvent ionizing power
| - Aromatic Ring Parameter
- Correlation
- Correlation coefficient
- Nucleophilic solvation
- Transition state
- Unimolecular
- Bimolecular
- Kinetics
| - Substituent effects
- Carbocations
- Solvent effects
- Nucleophilic substitution
- Activation parameters
- Electrofugality
- Electrophilicity
|
Submission
Deadline for Submissions: 1 December 2008
Submitted papers
should not have been previously published nor be currently under
consideration
for publication elsewhere. All papers are refereed through a peer
review
process. A guide for authors, sample copies and other relevant
information for
submitting papers are available on the “Instructions
for Authors” page.
The International Journal of Molecular Sciences
is an international peer-reviewed monthly journal published by The
Molecular
Diversity Preservation International.
Call for Papers
Announced Papers
(none)
Published Papers
Malcolm J. D’Souza 1,*, Lamia Yaakoubd 1, Stacey L. Mlynarski 1, and Dennis N. Kevill 2,*1 Department of Chemistry, Wesley College, 120 N. State Street, Dover, Delaware 19901-3875, USA; E-mail:
[email protected]2
Department of Chemistry and Biochemistry, Northern Illinois University,
DeKalb, Illinois 60115-2862, USA; E-mail:
[email protected] * Authors to whom correspondence should be addressed
Received: 11 April 2008; in revised form: 19 May 2008 / Accepted: 19 May 2008 / Published: 24 May 2008Article: Concerted Solvent Processes for Common Sulfonyl Chloride Precursors used in the Synthesis of Sulfonamide-based DrugsInt. J. Mol. Sci. 2008,
9, 914-925 (PDF format, 283K); DOI:
10.3390/ijms9050914
Marina C. Reis 1, Ruben Elvas-Leitão 2 and Filomena Martins 1,*1
Department of Chemistry and Biochemistry, Sciences Faculty, University
of Lisbon, CQB, Campo Grande, 1749-016 Lisboa, Portugal. E-Mail:
[email protected] (M. R.)
2 Department of Chemical Engineering,
Lisbon Institute of Engineering, IPL, R. Conselheiro Emídio Navarro, 1,
1959-007 Lisboa, Portugal. E-Mail:
[email protected] (R. E-L.)
*
Author to whom correspondence should be addressed; E-Mail:
[email protected]; Tel. +351-21-7500870; Fax: +351-21-7500088
Received: 17 June 2008; in revised form: 4 August 2008 / Accepted: 26 August 2008 / Published: 4 September 2008Article: The Influence of Carbon-Carbon Multiple Bonds on the Solvolyses of Tertiary Alkyl Halides: a Grunwald-Winstein AnalysisInt. J. Mol. Sci. 2008,
9, 1704-1716 (PDF format, 125K); DOI:
10.3390/ijms9091704
Leading Papers and Reviews- D’Souza,
M. J.; Reed, D.; Koyoshi, F.; Kevill, D. N. Consideration of the Factors
Influencing the Specific Rates of Solvolysis of p-Methoxyphenyl Chloroformate.
Int. J. Mol.
Sci. 2007, 8, 788-796
- Kevill,
D. N.; Koyoshi, F.; D’Souza M. J. Correlations
of the Specific Rates of Solvolysis of Aromatic Carbamoyl Chlorides,
Chloroformates, Chlorothionoformates, and Chlorodithioformates Revisited. Int. J. Mol.
Sci.
2007, 8, 346-362
- Kyong,
J. B.; Chan, J. R.; Kim, Y.-G.; Kevill, D. N.
Rate and Product Studies with 2-Adamantyl
Fluoroformate Under Solvolytic Conditions.
J. Phys. Org.
Chem. 2007, 20, 525-531
- Kevill,
D. N.; Ryu, Z. H.; Niedermeyer, M. A.; Koyoshi, F.; D’Souza, M. J. Rate and
Product Studies in the Solvolyses of Methanesulfonic Anhydride and a Comparison
with Methanesulfonyl Chloride Solvolyses. J. Phys. Org.
Chem. 2007, 20, 431-438
- Fujita,
M.; Mishima, E.; Okuyama, T. Solvolysis of
Methoxy-Substituted Diaryliodonium Tetrafluoroborates: Attempted Generation of
a Stabilized Aryl Cation. J. Phys. Org.
Chem. 2007, 20, 241-244
- Kevill,
D. N.; Koh, H. J. Correlation of the Rates of Solvolysis of Diphenylphosphinyl Chloride
Using an Extended Form of the Grunwald-Winstein Equation. J. Phys. Org.
Chem. 2007, 20, 88-92
- Creary, X.; O'Donnell, B. D.;
Vervaeke, M. Homoallyl-Cyclopropylcarbinyl
Cation Manifold. Trimethylsilyl versus Aryl Stabilization. J. Phys. Org.
Chem. 2007, 9, 3360-3368
- Kevill, D. N.; Kyong, J. B. Intramolecular
Nucleophilic Assistance in the Solvolyses of Benzyl Derivatives: Solvolyses of o-Nitrobenzyl Bromide and Tosylate. J. Phys. Org.
Chem. 2007, 210-215
- Berger, S. T. A.; Seeliger, F. H.; Hofbauer, F.; Mayr,
H. Electrophilicity Parameters for 2-Benzylidene-indan-1,3-diones-A
Systematic Extension of the Benzhydrylium Based Electrophilicity Scale. Org.
Biomol. Chem. 2007, 18, 3020-3026
- Lee, S. H.; Rhu, C. J.; Kyong, J. B.; Kim, D.
K.; Kevill, D. N. Correlation of the Rates
of Solvolysis of Isopropyl Fluoroformate Using the Extended Grunwald-Winstein
Equation. Bull. Korean Chem. Soc. 2007, 28, 657-661
- Liu, K. –T.; Chang, L. –W. ; Chin, C. –P. Kinetic Evidence for the Solvent
Intervention in the Solvolysis of Tertiary Benzylic Benzoates. Chin.
J. Chem. 2006, 24, 1238-1241
- Bentley, T. W. Additivity Rules Using Similarity Models for
Chemical Reactivity: Calculation and Interpretation of Electrofugality and
Nucleofugality. Chem. Eur. J. 2006, 12, 6514-6520
- Bentley, T. W.; Garley, M.
S. Correlations and Predictions of
Solvent Effects on Reactivity: Some Limitations of Multi-Parameter Equations
and Comparisons with Similarity Models Based on One Solvent Parameter. J. Phys. Org.
Chem.
2006, 19, 341-349
- Kevill,
D. N.; Park, B. C.; Park, K. H.; D’Souza, M. J.; Yaakoubd, L.; Mlynarski, S.
L.; Kyong, J. B. Rate and Product Studies in the Solvolyses of
N,N-dimethylsulfamoyl and 2-Propanesulfonyl Chlorides. Org.
Biomol. Chem. 2006, 4, 1580-1586
- D’Souza,
M. J.; Boggs, M.E.; Kevill, D. N. Correlation of the Rates
of Solvolysis of 2-Furancarbonyl Chloride & Three Naphthoyl Chlorides. J. Phys. Org.
Chem. 2006, 173-178
- Denegri, B.; Streiter,
A.; Juri, S.; Ofial, A. R.;
Kronja, O.; Mayr, H. Kinetics of the Solvolyses of Benzhydryl Derivatives: Basis for the
Construction of a Comprehensive Nucleofugality Scale. Chem.
Eur. J. 2006, 12, 1648-1656
- Kevill, D. N.; Ryu, Z. H. Additional Solvent Ionizing Power Values for
Binary Water-1,1,1,3,3,3-Hexafluoro-2-propanol Solvents.
Int. J. Mol.
Sci.
2006, 7, 451-455
- Kyong, J. B.; Ryu, S. H.; Kevill, D. N. Rate
and Product Studies of Solvolyses of Benzyl Fluoroformate.
Int. J. Mol.
Sci. 2006, 7, 186-196
- Kevill, D. N.; Goken, E. G.; Park, B. C. Correlation of the
Specific Rates of Solvolysis of Trimethylsilylmethyl Trifluoromethanesulfonate
Using a Two-term Grunwald-Winstein Equation.
J. Chem. Res. 2006, 173-175
- Fujio, M.; Umezaki, Y.; Alam,
Md. A.; Kikukawa, K.; Fujiyama,
R.; Tsuno, Y. The β-Silicon Effect. II.
Substituent Effects on the Solvolysis of 1-Aryl-2-(aryldimethylsilyl)ethyl
3,5-Dinitrobenzoates. Bull. Chem. Soc. Jap. 2006,
79, 1091-1099